Aromatic polycarbonate polarising lens

ABSTRACT

Provided is a polarizing lens which is excellent in terms of impact resistance, outer appearance and prevention of eye strain and which exhibits little variation in color tone and transmittance during formation. The polarizing lens is formed by stretching a polyvinyl alcohol film and dyeing it with a dichroic dye, bonding an aromatic polycarbonate sheet to both surfaces of the film by means of an adhesive layer, and then inserting a polarizing sheet, bent to have a spherical or aspherical surface, into a mold, and injecting aromatic polycarbonate thereto, wherein the area in which the dichroic dye seeps from the surface of the polyvinyl alcohol film is not more than a quarter of the thickness of the polyvinyl alcohol film.

TECHNICAL FIELD

The present invention relates to a polarizing lens obtained bysubjecting a polarizing sheet to a bending process to provide a bentsurface shape, or a polarizing lens constituted of an aromaticpolycarbonate, which is formed by subjecting a polarizing sheet to abending process to provide a bent surface shape, and then injecting thearomatic polycarbonate to one of the surfaces of the polarizing sheet.

BACKGROUND ART

Polarizing sheets constituted of a polycarbonate have excellent impactresistance and are light, and therefore are used for liquid crystaldisplays as well as windows of buildings, sunroofs of cars, andsunglasses or goggles to be used for marine sports, winter sports,fishing, etc.

Polarizing sheets, which are obtained by laminating an aromaticpolycarbonate sheet as a protection layer through an adhesive layer toeach surface of a polarizing film obtained by stretching a polyvinylalcohol film and dyeing it with a dichroic dye (hereinafter referred toas “aromatic polycarbonate polarizing sheet”), particularly haveexcellent impact resistance and also have high heat resistance, andtherefore are used for polarizing lenses for sunglasses or gogglesobtained from a bending process or injection molding process.

However, since aromatic polycarbonate has a high photoelastic constant,when a bending process is applied to a spherical or aspherical shape ofsunglasses, goggles or the like, a coloring interference stripe tends toeasily occur due to retardation. Such a coloring interference stripe hasproblems such as poor outer appearance and causing eye strain.

Further, in the case of a polarizing lens obtained by subjecting anaromatic polycarbonate polarizing sheet to a bending process to providea spherical or aspherical shape, distortion of an image may be caused byunevenness of the thickness of the aromatic polycarbonate polarizingsheet, and there are problems such as poor outer appearance and causingeye strain.

Regarding retardation caused at the time of applying a bending process,an aromatic polycarbonate polarizing sheet, whose coloring interferencestripe has been hidden from view by subjecting an aromatic polycarbonatesheet to be used for a protection layer to a stretching process to causea large retardation in advance (hereinafter referred to as “stretchedpolycarbonate polarizing sheet”), is known (Patent Document 1), and isused for polarizing lens products which have excellent outer appearanceand are excellent in saving eye strain.

Meanwhile, a polarizing lens, which is formed by subjecting theafore-mentioned stretched polycarbonate polarizing sheet to a bendingprocess to provide a spherical or aspherical shape, inserting theresultant stretched polycarbonate polarizing sheet into a mold andinjecting an aromatic polycarbonate thereto, for the purpose ofimproving impact resistance more than that of a polarizing lens formedby subjecting the afore-mentioned stretched polycarbonate polarizingsheet to a bending process or forming a corrective lens having a focalrefractive power (hereinafter referred to as “aromatic polycarbonatepolarizing lens”), is known (Patent Documents 2 and 3).

In the case of the aromatic polycarbonate polarizing lens, an aromaticpolycarbonate is injected and filled in a mold, and therefore, there isan advantage that unevenness of the thickness of the inserted stretchedpolycarbonate sheet becomes invisible. Therefore, the aromaticpolycarbonate polarizing lens is used for lens products without focalrefractive power which are particularly excellent in impact resistance,outer appearance and prevention of eye strain.

In the case of a lens obtained by filling a mold with a thermosettingresin or thermoplastic resin as in the case of the aromaticpolycarbonate polarizing lens, the shape of each surface and thethickness of the formed lens can be freely set by suitably setting eachsurface shape of molds for the lens surfaces and the distance betweenthe surfaces. Therefore, the surface shapes of molds and the distancebetween the surfaces are set based on the optical design so that thefocal refractive power, prism diopter and image distortion of the formedlens become desired values.

In many cases, the surface shape of the formed lens is the same as thesurface shape of the mold contacted at the time of forming, but when thesurface shape of the lens requires very high precision, in order tocompensate decrease of the lens thickness and change of the surfaceshape due to volume contraction at the time of solidification of thethermosetting resin or thermoplastic resin filled in the mold, thesurface shapes of molds for both the surfaces and the distance betweenthe surfaces may be suitably and finely adjusted.

On the surface of the aromatic polycarbonate polarizing lens formed inthis way, a hard coating, an antireflection film and the like aresuitably formed, and then the lens is fixed to a frame by edging, holemaking, screw tightening, etc., thereby providing sunglasses or goggles.

In the meantime, in the case of polarizing lenses in which an aromaticpolycarbonate polarizing sheet is subjected to a bending process toprovide a spherical or aspherical shape or aromatic polycarbonatepolarizing lenses, for the purpose of reducing the glare of a glasssurface, water surface, etc., polarized light in the horizontaldirection is cut. In addition, for the purpose of improving visibilityor design, for example, an aromatic polycarbonate polarizing sheetcolored in grey, brown or the like is used to provide a desired colortone and transmittance.

In order to increase the polarization degree of a polarizing lens, theamount of a dichroic dye dyeing a polyvinyl alcohol film is adjusted toobtain a concentration at which a polarization component in thehorizontal direction of light incident on the polarizing lens is almostabsorbed, and when the amount of the dichroic dye dyeing the polyvinylalcohol film is further increased, a polarization component in theperpendicular direction of light incident on the polarizing lens is alsoabsorbed in a large amount.

Further, regarding the dichroic dye for dyeing the polyvinyl alcoholfilm, not single, but several colors of dichroic dyes are used. In thisregard, by changing the amount of each dichroic dye for dyeing thepolyvinyl alcohol film, a polarizing lens having a desired color toneand transmittance can be obtained.

Further, it is also possible to adjust the color tone and transmittanceof the aromatic polycarbonate polarizing sheet by using a dye-dissolvedproduct in an adhesive layer or an aromatic polycarbonate sheet of aprotection layer, or by using it in combination with the aforementionedmethod.

PRIOR ART DOCUMENTS Patent Documents

-   Patent Document 1: Japanese Laid-Open Patent Publication No.    H03-39903-   Patent Document 2: Japanese Laid-Open Patent Publication No.    H08-52817-   Patent Document 3: Japanese Laid-Open Patent Publication No.    H08-313701

SUMMARY OF THE INVENTION Problems to be Solved by the Invention

As described above, an aromatic polycarbonate polarizing sheet issubjected to a bending process to provide a spherical or asphericalshape, or an aromatic polycarbonate polarizing sheet subjected to abending process is then inserted into a mold, to which aromaticpolycarbonate is injected, thereby obtaining a polarizing lens which isexcellent in terms of impact resistance, outer appearance and preventionof eye strain.

However, in the case of an aromatic polycarbonate polarizing lensobtained by subjecting an aromatic polycarbonate polarizing sheet to abending process to provide a spherical or aspherical shape or anaromatic polycarbonate polarizing lens obtained by further subjectingthe sheet to injection molding, the color tone and transmittance of thearomatic polycarbonate polarizing sheet significantly change before andafter molding of the polarizing lens, and as a result, there is aproblem that the difference among products is increased.

It was found by studies that at the time of forming an aromaticpolycarbonate polarizing lens by means of injection molding, an aromaticpolycarbonate polarizing sheet after subjected to the bending process issubjected to injection molding while being cooled by a mold, andtherefore the color tone and transmittance of the aromatic polycarbonatepolarizing sheet are changed just a little and not changedsubstantially.

However, it was also found that, in the case of a polarizing lensobtained by subjecting an aromatic polycarbonate polarizing sheet to thebending process to provide a spherical or aspherical shape or anaromatic polycarbonate polarizing lens, since heating at the time of thebending process is carried out to a temperature around theglass-transition temperature of the aromatic polycarbonate used for thepolarizing sheet, the color tone and transmittance of the aromaticpolycarbonate polarizing sheet significantly change, resulting insignificant difference between products.

In particular, there is a problem that, in the case of an aromaticpolycarbonate polarizing lens having a high dye concentration and a lowtransmittance, the color tone and transmittance of the aromaticpolycarbonate polarizing sheet after molding are significantly changedfrom those before molding compared to an aromatic polycarbonatepolarizing lens having a low dye concentration and a high transmittance.

In addition, there is a problem that, when the color tone andtransmittance after molding significantly change from those beforemolding, the variations of the color tone and transmittance are notconstant, resulting in differences of the color tone and transmittancebetween products after molded.

Means for Solving the Problems

The present invention is a polarizing lens, which is formed bystretching a polyvinyl alcohol film and dyeing the film with a dichroicdye, bonding an aromatic polycarbonate sheet to both surfaces of thefilm via an adhesive layer and bending the obtained product to have aspherical or aspherical surface, wherein the area in which the dichroicdye seeps from the surface of the polyvinyl alcohol film is not morethan a quarter of the thickness of the polyvinyl alcohol film, andwherein the central portion in the thickness direction of the polyvinylalcohol film is not dyeing with the dichroic dye.

Further, the present invention is a polarizing lens, which is formed bystretching a polyvinyl alcohol film and dyeing the film with a dichroicdye, bonding an aromatic polycarbonate sheet to both surfaces of thefilm via an adhesive layer, bending the obtained product to have aspherical or aspherical surface and injecting an aromatic polycarbonateto one of the surfaces of the polarizing sheet, wherein the area inwhich the dichroic dye seeps from the surface of the polyvinyl alcoholfilm is not more than a quarter of the thickness of the polyvinylalcohol film, and wherein the central portion in the thickness directionof the polyvinyl alcohol film is not dyeing with the dichroic dye.

Advantageous Effect of the Invention

According to the present invention, it is possible to stably provide anaromatic polycarbonate polarizing lens, which exhibits little variationin the color tone and transmittance before and after forming into thepolarizing lens, and which provides little difference between products.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows a cross sectional view of an aromatic polycarbonatepolarizing lens according to the present invention.

FIG. 2 shows photographs of cross-sectional surfaces of polarizing filmsto be used in an aromatic polycarbonate polarizing lens according to thepresent invention. Photograph [A] corresponds to Sample No. [1] ofComparative Example 1, and photographs [B] to [E] correspond to SampleNos. [2] to [5] of Example 1, respectively.

FIG. 3 shows photographs of cross-sectional surfaces of polarizing filmsto be used in an aromatic polycarbonate polarizing lens according to thepresent invention. Photographs [F] to [I] correspond to Sample Nos. [6]to [9] of Example 2, respectively.

FIG. 4 shows photographs of cross-sectional surfaces of polarizing filmsto be used in an aromatic polycarbonate polarizing lens according to thepresent invention. Photographs [J] to [M] correspond to Sample Nos. [10]to [13] of Example 3, respectively.

EMBODIMENTS FOR CARRYING OUT THE INVENTION

The aromatic polycarbonate polarizing lens of the present invention willbe described below.

Firstly, a resin film as a base material for a polarizing film isswollen in water, and then immersed in a dyeing solution containing adye such as a dichroic dye while being directionally stretched todisperse the dichroic dye in the base resin in an oriented state,thereby obtaining a polarizing film to which polarization propertieshave been imparted.

As the resin as the base material for the polarizing film to be used inthis case, polyvinyl alcohols may be used. As the polyvinyl alcohols,polyvinyl alcohol (hereinafter referred to as “PVA”), PVA in which aslight amount of the acetic acid ester structure remains, and PVAderivatives, or polyvinyl formal that is an analog, polyvinyl acetal,saponified ethylene-vinyl acetate copolymer, etc. are preferred, and PVAis particularly preferred.

Further, regarding the molecular weight of a PVA film, from theviewpoint of stretchability and film strength, the weight-averagemolecular weight is preferably 50,000 to 350,000, and particularlypreferably 150,000 to 300,000. The scaling factor of stretching of thePVA film is preferably 2- to 8-fold, and particularly preferably 3- to5-fold from the viewpoint of the dichroic ratio and film strength afterstretching. The thickness of the PVA film after stretching is notparticularly limited, but because the film tears easily when it is thinand the light transmission of the film is reduced when it is thick, thethickness of the film is preferably about 20 to 50 μm.

Further, as a dye to be used in this case, from the viewpoint of dyeingproperties with respect to the PVA film and heat resistance, a directdye consisting of an azo dye having a sulfonic acid group is preferred,and direct dyes of respective colors are dissolved or dispersed in adyeing solution at a concentration at which a desired color tone andtransmittance of the polarizing film can be obtained. In addition to thedirect dyes, an inorganic salt such as sodium chloride and sodiumsulfate, as a dyeing aid, is suitably added to the dyeing solution.

The present inventors found that change in the color tone andtransmittance when producing an aromatic polycarbonate polarizing sheetand subjecting it to the bending process while maintaining itsprocessability so as not to generate a crack in a polarizing film variesdepending on the depth of the area in which a dye seeps from the surfaceof a resin film as a base material of the polarizing film, and that thedeeper the area in which the dye seeps from the surface of the resinfilm as the base material of the polarizing film is, the more the changein the color tone and transmittance when subjecting the sheet to thebending process while maintaining its processability so as not togenerate a crack in the polarizing film increases.

Specifically, the present inventors found that when the area in whichthe dye seeps from the surface of the resin film as the base material ofthe polarizing film is shallow, the change in the color tone andtransmittance when subjecting the sheet to the bending process whilemaintaining its processability so as not to generate a crack in thepolarizing film is small, and that particularly when the area in whichthe dye seeps from the surface of the resin film as the base material ofthe polarizing film is not more than a quarter of the thickness of theresin film, the change in the color tone and transmittance whensubjecting the sheet to the bending process while maintaining itsprocessability so as not to generate a crack in the polarizing film issmall.

The depth of the area in which the dye seeps from the surface of theresin film can be adjusted by the temperature of the dyeing solution andthe immersion time.

When the temperature of the dyeing solution is too high, the resin filmas the base material of the polarizing film is dissolved therein, andwhen the temperature is too low, the rate of seeping of the dye is tooslow and this requires dyeing for a long period of time, result inreduction of productivity, or it becomes difficult to control thetemperature because it is too close to room temperature. Therefore, thetemperature of the dyeing solution in the case of the PVA film ispreferably 20° C. to 70° C., and particularly preferably 30° C. to 45°C.

The immersion time is selected such that the depth of the area in whichthe dye seeps from the surface of the resin film as the base material ofthe polarizing film becomes desirable.

Preferably, the polarizing film is further treated with a metal compoundand boric acid because it imparts excellent heat resistance and solventresistance to the polarizing film.

Specifically, the polarizing film can be treated by using a method inwhich the polarizing film dyeing in a solution of a dichroic dye isstretched during or after immersing in a mixed solution of a metalcompound and boric acid, or a method in which the polarizing film dyeingand stretched in a solution of a dichroic dye is immersed in a mixedsolution of a metal compound and boric acid.

As the metal compound, transition metals belonging to Period 4, Period 5and Period 6 may be used. Among such metal compounds, those whoseeffects of heat resistance and solvent resistance have been confirmedexist, but from the viewpoint of the cost, metal salts such as acetate,nitrate and sulfate of fourth-period transition metals such as chromium,manganese, cobalt, nickel, copper and zinc are preferred. Among them,compounds of nickel, manganese, cobalt, zinc and copper are morepreferred because they are inexpensive and excellent in theaforementioned effects.

More specific examples thereof include manganese (II) acetatetetrahydrate, manganese (III) acetate dihydrate, manganese (II) nitratehexahydrate, manganese (II) sulfate pentahydrate, cobalt (II) acetatetetrahydrate, cobalt (II) nitrate hexahydrate, cobalt (II) sulfateheptahydrate, nickel (II) acetate tetrahydrate, nickel (II) nitratehexahydrate, nickel (II) sulfate hexahydrate, zinc (II) acetate, zinc(II) sulfate, chromium (III) nitrate nonahydrate, copper (II) acetatemonohydrate, copper (II) nitrate trihydrate and copper (II) sulfatepentahydrate. Among these metal compounds, any one of them may be usedsolely, and alternatively, a plurality of types of compounds may be usedin combination.

Regarding the content of the metal compound and boric acid in thepolarizing film, from the viewpoint of imparting heat resistance andsolvent resistance to the polarizing film, the content of the metalcompound as a metal is preferably 0.2 to 20 mg, and more preferably 1 to5 mg per 1 g of the polarizing film. The content of boric acid as boronis preferably 0.3 to 30 mg, and more preferably 0.5 to 10 mg.

The composition of a treatment solution to be used for the treatment isset so as to satisfy the above-described contents. In general, it ispreferred that the concentration of the metal compound is 0.5 to 30 g/Land that the concentration of boric acid is 2 to 20 g/L.

Analysis of the content of metal and boron in the polarizing film can beconducted using atomic absorption spectrometry.

Regarding the immersion temperature for the step of immersion using themetal compound and boric acid, when the temperature is too high, a resinfilm as a base material of the polarizing film is dissolved, and whenthe temperature is too low, it is difficult to control the temperaturebecause it is too close to room temperature. Therefore, the immersiontemperature is preferably 20 to 70° C., and particularly preferably 30to 45° C. Further, the immersion time in the step of immersion using themetal compound and boric acid is preferably 0.5 to 15 minutes. Regardingconditions for the step of heating after immersion, heating is carriedout at a temperature of 70° C. or higher, preferably at a temperature of90 to 120° C. for 1 to 120 minutes, preferably for 3 to 40 minutes.

Next, a protection layer consisting of an aromatic polycarbonate sheetis laminated to each surface of the polarizing film through an adhesivelayer. As a resin material for the aromatic polycarbonate sheet to beused in this case, from the viewpoint of the film strength, heatresistance, durability or bending workability, polymers producedaccording to the well-known method from a bisphenol compound typified by2,2-bis(4-hydroxyphenyl)alkane or2,2-(4-hydroxy-3,5-dihalogenophenyl)alkane are preferred, and thepolymer skeleton thereof may include a structural unit derived from afatty acid diol or a structural unit having ester bonds. In particular,an aromatic polycarbonate induced from 2,2-bis(4-hydroxyphenyl)propaneis preferred.

Regarding the molecular weight of the aromatic polycarbonate sheet, fromthe viewpoint of forming of the sheet itself, the viscosity-averagemolecular weight is preferably 12,000 to 40,000, and from the viewpointof the film strength, heat resistance, durability or bendingworkability, the viscosity-average molecular weight is particularlypreferably 20,000 to 35,000. Regarding the retardation value of thearomatic polycarbonate sheet, from the viewpoint of suppression of acoloring interference stripe, the lower limit thereof is preferably2,000 nm or higher. The upper limit thereof is not particularly limited,but from the viewpoint of the film production, the upper limit ispreferably 20,000 nm or lower, and particularly preferably 4,000 nm orhigher and 20,000 nm or lower. When the retardation value is higher, acoloring interference stripe is not easily generated, but there is adisadvantage that the surface shape precision is lower.

When using the aromatic polycarbonate sheet having a high retardationvalue at the light incidence side of the polarizing film, i.e., theopposite side of the human eye, a coloring interference stripe is noteasily generated.

As an adhesive to be used for lamination of aromatic polycarbonate onthe surfaces of the polarizing film, an acrylic resin-based material, aurethane resin-based material, a polyester resin-based material, amelamine resin-based material, an epoxy resin-based material, asilicone-based material or the like may be used, and in particular, fromthe viewpoint of the adhesive layer itself or transparency and adhesionproperties with respect to aromatic polycarbonate at the time ofadhering, a two-component thermosetting urethane resin consisting ofpolyurethane prepolymer that is a urethane resin-based material and acuring agent is preferred. The aromatic polycarbonate polarizing sheetis obtained in this way.

The aromatic polycarbonate polarizing sheet to be used for the aromaticpolycarbonate polarizing lens of the present invention is not limited tothe aforementioned aromatic polycarbonate polarizing sheet. It is alsopossible to use an aromatic polycarbonate polarizing sheet also havingthe photochromic function, which is prepared using an adhesive in whicha photochromic dye is dissolved for adhesion between the polarizing filmand the aromatic polycarbonate of the protection layer. The similareffects can be obtained by a polarizing lens formed by subjecting anaromatic polycarbonate sheet to be used for the protection layer of thepolarizing film to the stretching treatment in advance to provide astretched polycarbonate polarizing sheet in which a large retardationhas been generated, subjecting the stretched polycarbonate polarizingsheet to the bending process to impart spherical or aspherical surfacesthereto, and inserting the polarizing sheet into a mold and injectingthe aromatic polycarbonate thereon in the above-described way.

Next, the stretched polycarbonate polarizing sheet is subjected to thebending process.

Conditions for the bending process of the stretched polycarbonatepolarizing sheet are not particularly limited, but the sheet must bebent so that it fits the surface of a mold to be used for injectionmolding. Further, in the case of the polarizing film, a crack in thestretching direction, so-called film cutting tends to be easilygenerated in the bending process. In view of these points, the moldtemperature in the bending process of the stretched polycarbonatepolarizing sheet is preferably a temperature around the glass-transitiontemperature of the aromatic polycarbonate used for the stretchedpolycarbonate polarizing sheet. In addition, the temperature of thestretched polycarbonate polarizing sheet immediately prior to thebending process is preferably adjusted to a temperature which is equalto or higher than a temperature 50° C. lower than the glass-transitiontemperature of the aromatic polycarbonate and lower than theglass-transition temperature by means of the preheating treatment, andparticularly preferably adjusted to a temperature which is equal to orhigher than a temperature 40° C. lower than the glass-transitiontemperature and lower than a temperature 5° C. lower than theglass-transition temperature.

Next, the aromatic polycarbonate may be injected to the stretchedpolycarbonate polarizing sheet.

Conditions for injection molding are not particularly limited, butexcellent outer appearance is required. From this viewpoint, the moldtemperature is preferably a temperature which is equal to or higher thana temperature 50° C. lower than the glass-transition temperature of thearomatic polycarbonate used for the stretched polycarbonate polarizingsheet and lower than the glass-transition temperature, and particularlypreferably a temperature which is equal to or higher than a temperature40° C. lower than the glass-transition temperature and lower than atemperature 15° C. lower than the glass-transition temperature.

Next, the hard coating treatment may be carried out.

Materials of hard coating and processing conditions are not particularlylimited, but excellent outer appearance and adhesiveness with respect tothe aromatic polycarbonate as the base or inorganic layers such as amirror coat and an antireflection coat to be subsequently coated arerequired. From this viewpoint, the burning temperature is preferably atemperature which is equal to or higher than a temperature 50° C. lowerthan the glass-transition temperature of the aromatic polycarbonate usedfor the stretched polycarbonate polarizing sheet and lower than theglass-transition temperature, and particularly preferably a temperaturewhich is equal to or higher than a temperature 40° C. lower than theglass-transition temperature and lower than a temperature 15° C. lowerthan the glass-transition temperature, i.e., a temperature around 120°C. The time required for burning the hard coat is about 30 minutes to 2hours.

EXAMPLES

Hereinafter, the present invention will be specifically described by wayof illustrative examples, but the present invention is not limitedthereto.

In general, a color tone in the case of using several colors of dyes canbe calculated from the sum of absorbance of respective dyes used at 380to 780 nm using the XYZ colorimetric system or L*a*b* colorimetricsystem.

The same calculation method can be employed in the case of polarizingfilms in which desired color tone and transmittance are obtained byusing several colors of dichroic dyes and changing the amounts of dyeingof the respective dichroic dyes in a polyvinyl alcohol film, and colortones before and after forming an aromatic polycarbonate polarizingsheet can also be calculated from the sum of absorbance values ofrespective dichroic dyes before and after forming. In the workingexamples of the present invention, a single color of dichroic dye wasused and the transmittance and color tone before and after forming weremeasured to obtain color difference.

Comparative Example 1 (a) Polarizing Film

Polyvinyl alcohol (Kuraray Co., Ltd., trade name: VF-PS#7500) wasswollen in water at 35° C. for 270 seconds while being stretched 2-fold.After that, it was dyeing in an aqueous solution containing SumilightRed 4B (C.I.28160) and 10 g/L of anhydrous sodium sulfate at 35° C.

This dyeing film was immersed in an aqueous solution containing 2.3 g/Lof nickel acetate and 4.4 g/L of boric acid at 35° C. for 120 secondswhile being stretched 4-fold. The film was dried at room temperature for3 minutes in a state where the tension was retained, and then subjectedto a heating treatment at 110° C. for 3 minutes, thereby obtaining apolarizing film.

The results of the measurement of the thickness of the obtainedpolarizing film and the area in which the dye seeped, and the dichroicratio of the polarizing film at 530 nm, which is the maximum absorptionwavelength of the dye used, are shown in Table 1 (Sample No. [1]). Thedichroic ratio was obtained by the following formula:

Dichroic ratio=Az/Ax

In this regard, Ax represents an absorbance of linearly-polarized lightin the maximum transmission direction, and Az represents an absorbanceof linearly-polarized light in a direction perpendicular to the maximumtransmission direction. Ax and Az were measured by allowing thelinearly-polarized light to be incident on the sample, using aspectrophotometer manufactured by Shimadzu Corporation (UV-3600).

A photograph of the cross-sectional surface of the obtained polarizingfilm is shown in FIG. 2 [A]. The photograph was taken using an opticalmicroscope.

(b) Aromatic Polycarbonate Polarizing Sheet

A urethane-based adhesive was applied to the polarizing film obtained in(a) using a bar coater #12, and it was dried at 70° C. for 10 minutes.After that, an aromatic polycarbonate sheet having a thickness of 0.3 mmand a retardation value of 5500 nm (Mitsubishi Gas Chemical Co., Inc.)was bonded to the polarizing film using a laminating machine so thatboth the stretch axis of the aromatic polycarbonate sheet and thestretch axis of the polarizing film are in the horizontal direction ofthe polarizing lens.

The adhesive was applied to the polarizing film side of the laminatedsheet in the same manner as above, and another aromatic polycarbonatesheet was bonded thereto in the same way, thereby obtaining an aromaticpolycarbonate polarizing sheet. The thickness of the coated adhesiveafter curing was 9 to 11 μm.

(c) Measurement of Absorbance of Aromatic Polycarbonate Polarizing Lens

The transmittance and color tone of the prepared aromatic polycarbonatepolarizing sheet were measured using the spectrophotometer manufacturedby Shimadzu Corporation (UV-3600). The transmittance and the color toneobtained from the L*a*b* colorimetric system of Sample No. [1] are shownin Table 1.

(d) Aromatic Polycarbonate Polarizing Lens

The aromatic polycarbonate polarizing sheet obtained in (b) wassubjected to the bending process using a mold having a base curve of7.95 (curvature radius 66.67 mm). In the bending process, forming wascarried out under the following conditions: mold temperature: 137° C.,and retention time: 1200 seconds. The base curve as used herein refersto a curvature of the front surface of the lens, and it is a valueobtained by dividing 530 by the curvature radius (unit of millimeter).

There was no crack in the polarizing film of the aromatic polycarbonatepolarizing lens after the bending process.

The transmittance and color tone of the aromatic polycarbonatepolarizing lens after the bending process of Sample No. [1] measured ina manner similar to that in (c), and the color difference ΔE*ab in theCIE1976 (L*a*b*) color space before and after forming are shown inTable 1. The color difference was obtained by the following formula:

Color difference: (ΔE*ab=((ΔL*)²+(Δa*)²+(Δb*)²)^(1/2)

Example 1

Polarizing films, in which the amount of dyeing of the dichroic dye wasthe same and the area in which the dichroic dye seeps was changed, wereobtained in a manner similar to that in (a), except that the dyeconcentration and dyeing time in the dyeing process were changed. Thephotographs of cross-sectional surfaces of the obtained polarizing filmsare shown in [B] to [E] of FIG. 2.

Further, the results of the measurement of the thickness and the area inwhich the dye seeped of the obtained polarizing films, and the dichroicratios of the polarizing films are shown in Sample Nos. [2] to [5] inTable 1.

Next, the transmittance and color tone of the aromatic polycarbonatepolarizing lens before and after the bending process were measured andthe color difference was obtained in manners similar to those in (b),(c) and (d). The results of the measurement are shown in Sample Nos. [2]to [5] in Table 1.

The color difference of each of Sample Nos. [4] and [5], in which thearea in which the dye seeped was equal to or more than a third, wasequal to or more than 2.4, and the color difference of each of SampleNos. [2] and [3], in which the area in which the dye seeped was not morethan a fifth, was not more than 1.9.

Further, there was no crack in the polarizing film of the aromaticpolycarbonate polarizing lens after the bending process, and theprocessability of the lens was comparable to that of the aromaticpolycarbonate polarizing lens of Comparative Example 1.

TABLE 1 Film Area in Dichroic thick- which dye ratio of Color Sampleness seeps polarizing Color tone before bending process Color tone afterbending process difference No. (μm) (μm) film Transmittance (%) L* a* b*Transmittance (%) L* a* b* ΔE*ab Comparative [1] 29.7 13.7 10.8 12.041.2 −1.7 0.7 9.9 37.8 0.4 1.4 4.1 Example 1 Example 1 [2] 31.2 5.0 22.549.8 75.9 32.4 5.3 47.4 74.5 33.4 5.0 1.8 [3] 31.1 6.5 21.2 48.5 75.132.9 6.0 46.3 73.7 34.1 5.6 1.9 [4] 31.4 10.0 19.0 46.4 73.8 34.7 6.544.0 72.2 36.4 6.0 2.4 [5] 31.7 12.0 17.8 45.2 73.0 35.7 7.0 43.6 72.038.1 6.2 2.8

Example 2

Polarizing films, in which the amount of dyeing of the dichroic dye wasthe same and the area in which the dichroic dye seeps was changed, wereobtained in a manner similar to that in Example 1, except that the filmwas stretched 4.4-fold in an aqueous solution containing nickel acetateand boric acid. The photographs of cross-sectional surfaces of theobtained polarizing films are shown in [F] to [I] of FIG. 3.

Further, the results of the measurement of the thickness and the area inwhich the dye seeped of the obtained polarizing films, and the dichroicratios of the polarizing films are shown in Sample Nos. [6] to [9] inTable 2.

Next, the transmittance and color tone of the aromatic polycarbonatepolarizing lens before and after the bending process were measured andthe color difference was obtained in manners similar to those in (b),(c) and (d). The results of the measurement are shown in Sample Nos. [6]to [9] in Table 2.

The color difference of each of Sample Nos. [8] and [9], in which thearea in which the dye seeped was equal to or more than a third, was 1.9,and the color difference of each of Sample Nos. [6] and [7], in whichthe area in which the dye seeped was not more than a quarter, was 1.4.

Further, there was no crack in the polarizing film of the aromaticpolycarbonate polarizing lens after the bending process, and theprocessability of the lens was comparable to that of the aromaticpolycarbonate polarizing lens of Comparative Example 1.

TABLE 2 Area in Dichroic Film which dye ratio of Color Sample thicknessseeps polarizing Color tone before bending process Color tone afterbending process difference No. (μm) (μm) film Transmittance (%) L* a* b*Transmittance (%) L* a* b* ΔE*ab Example 2 [6] 30.0 4.9 26.9 51.8 77.230.5 5.3 50.1 76.1 31.3 5.1 1.4 [7] 29.8 6.9 25.3 49.5 75.8 31.7 6.047.8 74.7 32.6 5.8 1.4 [8] 29.7 10.2 22.5 48.8 75.3 32.7 6.3 46.7 74.033.9 5.8 1.9 [9] 29.6 12.1 22.0 48.3 75.0 33.1 6.3 46.2 73.7 34.4 6.01.9

Example 3

Polarizing films, in which the amount of dyeing of the dichroic dye wasthe same and the area in which the dichroic dye seeps was changed, wereobtained in a manner similar to that in Example 1, except that the filmwas stretched 4.8-fold in an aqueous solution containing nickel acetateand boric acid. The photographs of cross-sectional surfaces of theobtained polarizing films are shown in [J] to [M] of FIG. 4.

Further, the results of the measurement of the thickness and the area inwhich the dye seeped of the obtained polarizing films, and the dichroicratios of the polarizing films are shown in Sample Nos. [10] to [13] inTable 3.

Next, the transmittance and color tone of the aromatic polycarbonatepolarizing lens before and after the bending process were measured andthe color difference was obtained in manners similar to those in (b),(c) and (d). The results of the measurement are shown in Sample Nos.[10] to [13] in Table 3.

The color difference of Sample No. [13], in which the area in which thedye seeped was about a half, was 2.4, and the color difference of eachof Sample Nos. [10] to [12], in which the area in which the dye seepedwas not more than a third, was not more than 1.7.

Further, there was no crack in the polarizing film of the aromaticpolycarbonate polarizing lens after the bending process, and theprocessability of the lens was comparable to that of the aromaticpolycarbonate polarizing lens of Comparative Example 1.

TABLE 3 Area in Dichroic Film which dye ratio of Color Sample thicknessseeps polarizing Color tone before bending process Color tone afterbending process difference No.1 (μm) (μm) film Transmittance (%) L* a*b* Transmittance (%) L* a* b* ΔE*ab Example 3 [10] 28.5 5.0 30.3 52.877.7 29.4 5.1 50.6 76.4 30.3 4.7 1.7 [11] 26.6 6.4 29.9 51.7 77.1 30.05.7 49.6 75.8 30.9 5.4 1.6 [12] 27.1 9.8 26.1 50.3 76.2 30.9 6.1 48.174.9 31.9 5.7 1.7 [13] 27.1 12.1 26.0 48.5 75.2 31.6 7.0 45.9 73.5 33.26.3 2.4

As is clearly understood from the working examples, in the case of thearomatic polycarbonate polarizing lens comprising a conventionalpolarizing film in which the area in which the dichroic dye seeps fromthe surface of the polyvinyl alcohol film is equal to or more than aquarter of the thickness of the polyvinyl alcohol film, the colordifference before and after processing is large, whereas in the case ofthe aromatic polycarbonate polarizing lens comprising the polarizingfilm of the present invention, in which the area in which the dichroicdye seeps from the surface of the polyvinyl alcohol film is not morethan a quarter of the thickness of the polyvinyl alcohol film and thecentral portion in the thickness direction of the polyvinyl alcohol filmis not dyeing with the dichroic dye, the color difference before andafter processing is small and the change in the color tone andtransmittance before and after the bending process is small.

EXPLANATIONS OF LETTERS OR NUMERALS

-   1 polarizing film-   2, 3 aromatic polycarbonate sheet-   4, 5 adhesive layer-   6 aromatic polycarbonate-   7 cross-sectional surface of polarizing film-   8 area in which dye seeps-   9 area in which dye does not seep

1. A polarizing lens, which is formed by stretching a polyvinyl alcoholfilm and dyeing the film with a dichroic dye, bonding an aromaticpolycarbonate sheet to both surfaces of the film via an adhesive layerand bending the obtained product to have a spherical or asphericalsurface, wherein the area in which the dichroic dye seeps from thesurface of the polyvinyl alcohol film is not more than a quarter of thethickness of the polyvinyl alcohol film, and wherein the central portionin the thickness direction of the polyvinyl alcohol film is not dyeingwith the dichroic dye.
 2. A polarizing lens, which is formed bystretching a polyvinyl alcohol film and dyeing the film with a dichroicdye, bonding an aromatic polycarbonate sheet to both surfaces of thefilm via an adhesive layer, bending the obtained product to have aspherical or aspherical surface and injecting an aromatic polycarbonateto one of the surfaces of the polarizing sheet, wherein the area inwhich the dichroic dye seeps from the surface of the polyvinyl alcoholfilm is not more than a quarter of the thickness of the polyvinylalcohol film, and wherein the central portion in the thickness directionof the polyvinyl alcohol film is not dyeing with the dichroic dye.